|
This data are believed to be current but is presented
here only as a broad indication.
For MSDS for a specific Battery product, you must rely ONLY on the
Manufacturers
current MSDS , a copy of which should be obtained from your Battery
product supplier.
-- Material Safety Data Sheet --
Valve Regulated Lead Acid Battery
" Battery Non-Spillable 49 CFR 173.195 (d)"
SECTION I
Manufacturer’s
Name: East Penn Manufacturing Co. Inc.
Lyon Station, PA 19536
|
Date:
May 2000.
Revised January 2007
Trade name. Gell: Absorbed Electrolyte, sealed valve regulated Non-Spillable Battery
|
| Emergency Telephone #:
CHEMTREC: 800-424-9300, in Washington DC or outside continental US call
202-483-7616 |
Distributed By:
M
& G Inc
2415 SW 3rd Ave;
Ft. Lauderdale Fl 33315.
Tel USA 954 525 5557 |
SECTION II
HAZARDOUS INGREDIENTS / IDENTITY
INFORMATION
Hazardous
Components Specific Chemical Identity (Common Name (s).) |
OSHA PEL |
ACGIH TLV |
Range % Percent
by weight |
Average |
| Lead, CAS #7439921 |
0.05mg/m3 |
0.15 mg/m3 |
60-75% |
67% |
| Sulfuric Acid, CAS #7664939 |
1.00 mg/m3 |
1.00 mg/m3 |
5-15% |
10% |
| Antimony, CAS #74403360 |
0.50 mg/m3 |
0.50 mg/m3 |
0-0.1% |
<0.1% |
| Arsenic, CAS
#7440382 |
0.01
mg/m3 |
.0.01
mg/m3 |
0-0.1% |
<0.01% |
| Polypropylene CAS#9003070 |
n/a |
n/a |
2-10% |
4% |
|
Calcium, CAS#7440702 |
1.0
mg/m3 |
1.0
mg/m3 |
0-0.1% |
<0.1% |
| Tin, CAS #7440702 |
2.0
mg/m3 |
2.0
mg/m3 |
0-0.1% |
<0.1% |
SECTION III
PHYSICAL/CHEMICAL CHARACTERISTICS
Electrolyte. (Sulfuric
Acid)
Appearance and Odor: Clear Odorless, colorless liquid.
Boiling Point:
235-240°F
Evaporation Rate (Butyl Acetate=1):
less than 1.0
Melting Point: N/A |
Solubility in Water: 100%
Specific Gravity (H20=1):1.270
-1.330
Vapor Density (AIR=1):Greater
than 1.
Vapor Pressure (mm Hg):
10 |
Section IV
FIRE AND EXPLOSION HAZARD DATA
| Flash Point (Method Used):
non-flammable Flammable Limit: *hydrogen gas
Extinguishing Media:
Class ABC extinguisher, CO2 and/or
Halon LEL: 4% UEL: 74%
Note: CO2 may be used, but not directly on the cell.
The thermal shock may cause cracking of the battery case and/or cases.
* Hydrogen gas may be generated during battery charging. |
| Special Fire Fighting Procedures: Cool
exterior of battery if exposed to fire to prevent rupture. The acid mist and vapors in a
fire situation are corrosive. Wear special respiratory protection (SCBA) and clothing. |
| Unusual Fire and Explosion Hazards: *When
overcharging this battery produces hydrogen gas, which may
explode if ignited. Use adequate ventilation, avoid open flames, sparks, or other sources
of ignition near battery. |
SECTION V
REACTIVITY DATA
Stability: Stable
Condition
to Avoid: Prolonged overcharging, sources of ignition.
Cases decompose at 160-410° C (322-770° F)
Incompatibility
(Materials to Avoid):
Sulfuric Acid: Contact with combustibles
and organic materials may cause fire and explosion
Also reacts violently with strong reducing agents, metals, strong oxidizers
and water. Contact with metals may produce toxic sulfur dioxide fumes and
may release flammable hydrogen gas.Hazardous Decomposition of By-Products:
Sulfuric Acid Excessive overcharging or fire may create Sulfur
Trioxide , carbon monoxide, sulfuric acid mist, sulfur dioxide and
hydrogen.
Lead Compounds: Contact with strong acid or base or presence of
nascent hydrogen may generate highly toxic arsine gas.
Case Material:
Polypropylene. Combustion can
produce carbon dioxide (CO2) and Carbon Monoxide (CO). Hazardous Decomposition of By-Products:
Sulfuric Acid Excessive overcharging or fire may create Sulfur
Trioxide , carbon monoxide, sulfuric acid mist, sulfur dioxide and
hydrogen.
Lead Compounds: Contact with strong acid or base or presence of
nascent hydrogen may generate highly toxic arsine gas.
Case Material:
Polypropylene. Combustion can
produce carbon dioxide (CO2) and Carbon Monoxide (CO). Hazardous Decomposition of By-Products:
Sulfuric Acid Excessive overcharging or fire may create Sulfur
Trioxide , carbon monoxide, sulfuric acid mist, sulfur dioxide and
hydrogen.
Lead Compounds: Contact with strong acid or base or presence of
nascent hydrogen may generate highly toxic arsine gas.
Case Material:
Polypropylene. Combustion can
produce carbon dioxide (CO2) and Carbon Monoxide (CO).
|
|
SECTION VI
HEALTH HAZARD DATA (Sulfuric Acid)
**NOT APPLICABLE TO NON - SPILLABLE SVR BATTERIES**
| Route(s) of Entry:
Not Applicable under
normal use. Carcinogenicity:
Sulfuric Acid; The International Agency for research
on cancer (IARC) has classified "strong inorganic acid mist containing
sulfuric acid" as a Category 1 carcinogen, a substance that is carcinogenic
to humans. This classification does not apply to liquid forms of sulfuric
acid contained within a battery. Inorganic acid mist (sulfuric acid mist) is
not generated under normal use of this product. Misuse of the product such
as overcharging, may result in the generation of sulfuric acid mist.
Lead Compounds. Lead is listed as a 2B carcinogen, likely in animals
in extreme doses. Proof of carcinogenicity in humans is lacking at present.
Arsenic: Listed by National Toxicology Program (NTP), IARC, OSHA, and
NIOSH as a carcinogen only after prolonged exposure at high levels.
Signs and Symptoms of Exposure:
Avoid contact with absorbed electrolyte
(sulfuric acid) may cause irritation of eyes, nose and throat. Contact with
eyes and skin causes irritation and skin burns. Absorbed electrolyte is
corrosive.
Medical Condition Generally Aggravated by Exposure:
Pregnant women and children must be protected from lead exposure.
|
| Health Hazards (Acute and Chronic):
Do not open battery, avoid contact with internal components. Internal
components include lead and absorbed electrolyte. Electrolyte is corrosive and contact may cause skin irritation and
chemical burns. |
Emergency and First Aid Procedures: (Contact
with internal components if battery is opened)
- Flush contacted area with large amounts of water for at least 15
minutes. Remove contaminated clothing and obtain medical attention if necessary.
Eye wash and emergency shower must be available.
- If swallowed, give large volumes of water. DO NOT induce
vomiting, and obtain medical treatment.
|
SECTION VII
PRECAUTIONS FOR SAFE HANDLING AND USE
**NOT APPLICABLE TO NON-SPILLABLE SVR BATTERIES**
| Steps to be Taken in Case Material is Released
or Spilled: Electrolyte material is corrosive. Contains sulfuric acid.
Neutralize any spilled materials. refernce 1996 North American Emergency
Response Guidebook, # 154. |
Waste Disposal Method: Lead-acid batteries
are completely recyclable. For information on returning Lead acid batteries for recycling,
call (954) 525-5557
or e'mail sales@mgbattery.com.
Disposal of lead acid batteries; Only in accordance with local, State or
applicable Federal regulations. |
| Precautions to be Taken in Handling and Storing:
Store away from reactive material as defined in Section V, Reactivity Data.
Place cardboard between layers of stacked batteries to avoid damage or short
circuit.Do not allow metallic materials to simultaneously contact both
battery terminals. |
| Other Precautions: If battery case is
broken, avoid direct contact with internal components. Keep away from ignition sources
during charging |
SECTION VIII
CONTROL MEASURES
| Respiratory Protection (Specific Type): N/A
Ventilation:
Must be provided when charging in an enclosed area.
Protective Gloves:
Recommended
Eye Protection:
Recommended
Other Protective Clothing or Equipment:
N/A
Work / Hygienic Practices:
Good personal hygiene and work
practices are recommended. |
SECTION IX
OTHER REGULATORY INFORMATION
.....................................................................................
| NFPA Hazard Rating |
Sulphuric acid |
lead |
| Health (Blue) |
3 |
3 |
| Flammability (Red) |
0 |
0 |
| Reactivity (Yellow) |
2 |
0 |
NOTE. Sulfuric Acid is water-reactive if
concentrated.
US DOT: The Non-Spillable
lead acid battery complies with the provisions listed in 49CFR173.159(d)
therefore must not be marked with an identification number such as UN2800, or a
hazard label such as corrosive. Also having passed IATA/ICAAO special provision
A67, these batteries are not subject to the air dangerous goods regulations.
RCRA: Spent lead-acid batteries are not regulated as hazardous
waste when recycled. Spilled sulfuric acid is a characteristic hazardous waste,
EPA hazardous waste number D002 (corrosivity).
CERCLA: (Superfund) and EPCRA Emergency
Planning And Community Right To Know ACT)
a) Reportable quantity (RQ) for spilled 100% sulfuric acid is
1000lbs.
b) Sulfuric acid is a listed "Extremely
Hazardous Substance" under EPCRA with a threshold Planning Quantity (TPQ) of
1000lbs.
c)
California Prop 65: This
product contains chemicals known to the State of California to cause cancer,
birth defects and other reproductive harm.
This information is accurate to the best of East Penn
Mfg Co's knowledge or obtained from sources believed by East Penn to be
accurate.
Before using any product read all warnings and directions
on the label.
=================================================================
Older MSDS Forms - Archival
only!
-- Material Safety Data Sheet --
BATTERY SEALED NON-SPILLABLE
Item 60682, DOT 173.159
Also known as Sealed Valve Regulated (SVR) Type
Batteries
SECTION I
|
Manufacturer’s Name: East Penn Manufacturing Co. Inc. |
Date
Prepared: Revised July 2000 |
|
Emergency Telephone #: CHEMTREC: 800-424-9300, in Washington DC
or outside continental US call 202-483-7616 |
Distributed By: M & G Inc 954 525 5557, 2415 SW 3rd Ave;
Ft. Lauderdale Fl 33315 |
SECTION II
HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
|
Hazardous Components Specific
Chemical Identity |
OSHA PEL |
ACGIH TLV |
Other Limits Recommended |
Percent |
| Lead, CAS #7439921 |
0.05 mg/m3 |
0.15 mg/m3 |
N/A |
40-70 |
| Sulfuric Acid, CAS
#7664939 |
1.00 mg/m3 |
1.00 mg/m3 |
N/A |
20-44 |
| Antimony, CAS #74403360 |
0.50 mg/m3 |
0.50 mg/m3 |
N/A |
0-4 |
SECTION III
PHYSICAL/CHEMICAL CHARACTERISTICS (Sulfuric Acid)
Older MSDS Form - Archival only!
**NOT APPLICABLE TO NON-SPILLABLE SVR BATTERIES**
| Appearance and Odor:
N/A
Boiling Point: N/A
Evaporation Rate (Butyl Acetate=1): N/A
Melting Point:
N/A |
Solubility in Water:
N/A
Specific Gravity (H20=1): N/A
Vapor Density (AIR=1): N/A
Vapor Pressure (mm Hg):
N/A |
Section IV
FIRE AND EXPLOSION HAZARD DATA
| Flash Point (Method
Used): non-flammable Flammable Limit:
*hydrogen gas
Extinguishing Media:
Class ABC extinguisher, CO2 and/or Halon
LEL: 4% UEL: 74% |
| Special Fire Fighting
Procedures: Cool exterior of battery if exposed to fire to prevent
rupture. The acid mist and vapors in a fire situation are corrosive. Wear
special respiratory protection (SCBA) and clothing. |
| Unusual Fire and
Explosion Hazards: *When overcharging this battery produces
hydrogen gas, which may explode if ignited. Use adequate ventilation,
avoid open flames, sparks, or other sources of ignition near battery. |
SECTION V
REACTIVITY DATA (Battery Case)
Older MSDS Forms - Archival only!
| Stability: Stable
Condition to Avoid: Cases decompose at 160-410°
C (322-770°
F)
Incompatibility (Materials to
Avoid): Strong oxidizing agents such as
hot nitric acid, etc.
Hazardous Decomposition of
By-Products: Combustion can produce
carbon dioxide (CO2) and Carbon Monoxide (CO).
Hazardous Polymerization:
will not occur. Conditions to Avoid:
N/A |
SECTION VI
HEALTH HAZARD DATA (Sulfuric Acid)
**NOT APPLICABLE TO NON-SPILLABLE SVR BATTERIES**
| Route(s) of Entry: N/A
Carcinogenicity: N/A
Signs and Symptoms of Exposure: N/A
Medical Condition Generally Aggravated by
Exposure: N/A |
| Health Hazards (Acute and
Chronic): Do not open battery, avoid contact with internal components.
Internal components include lead and gelled electrolyte. Electrolyte is
corrosive and contact may cause skin irritation and chemical burns.
|
Emergency and First Aid
Procedures: (Contact with internal components if battery is opened)
- Flush contacted area with large amounts of
water for at least 15 minutes. Remove contaminated clothing and obtain
medical attention if necessary.
- If swallowed, give large volumes of water.
DO NOT induce vomiting, obtain medical treatment.
|
SECTION VII
PRECAUTIONS FOR SAFE HANDLING AND USE
**NOT APPLICABLE TO NON-SPILLABLE SVR BATTERIES**
| Steps to be Taken in Case
Material is Released or Spilled: N/A |
| Waste Disposal Method:
Lead-acid batteries are completely recyclable. For information on
returning Lead acid batteries for recycling, call (954) 525-5557 |
| Precautions to be Taken in
Handling and Storing: Store away from reactive material as defined in
Section V, Reactivity Data. |
| Other Precautions: If
battery case is broken, avoid direct contact with internal components.
Keep away from ignition sources during charging |
SECTION VIII
CONTROL MEASURES
| Respiratory Protection (Specific
Type): N/A
Ventilation: Must be provided when
charging in an enclosed area.
Protective Gloves: N/A
Eye Protection: Recommended
Other Protective Clothing or Equipment:
N/A
Work / Hygienic Practices:
Good personal hygiene and work practices are
recommended. |
|
